{"created":"2023-05-15T09:01:36.975468+00:00","id":2365,"links":{},"metadata":{"_buckets":{"deposit":"36011c49-a9db-486e-a66d-2ad2bc44fdf0"},"_deposit":{"created_by":3,"id":"2365","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"2365"},"status":"published"},"_oai":{"id":"oai:hirosaki.repo.nii.ac.jp:00002365","sets":["375:380:440"]},"author_link":["6507","6509","6506","6510","6511","6508"],"item_5_alternative_title_21":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Photoinduced Hydrogen Production by Metalloporphyrin Doped in a Polymer Foam"}]},"item_5_alternative_title_22":{"attribute_name":"タイトル(ヨミ)","attribute_value_mlt":[{"subitem_alternative_title":"キンゾク ポルフィリン タンジ ハッポウ コウブンシマク ニオケル ヒカリユウキ スイソ セイサン"}]},"item_5_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-03-30","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"101","bibliographicPageEnd":"119","bibliographicPageStart":"115","bibliographic_titles":[{"bibliographic_title":"弘前大学教育学部紀要"}]}]},"item_5_description_17":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_5_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"機能性有機色素の金属ポルフィリン(TPP) を担持したPMMA 膜を,超臨界二酸化炭素流体(scCO2)を用いて発\n泡させ,光誘起水素発生システムに応用した.光誘起水素反応の構成成分として有機色素濃度,触媒濃度,照射光\n源の種類,有機色素の種類に注目して調べ,水素発生量及び水素発生速度の向上を試みた.その結果,有機色素と\nしてスズテトラフェニルポルフィリン(SnTPP) を担持したscCO2発泡PMMA 膜を用いた場合,SnTPP の濃度増加\nにより水素発生量が増加した.また,未発泡の膜をSnTPP の担持体に用いた場合よりも触媒である白金濃度が低\nい場合に水素発生速度の上昇が確認された.さらに,TPP の金属部位がニッケル,亜鉛のTPP についても調べた\nところ,耐光性に優れ水の還元において優位な電位を有するSnTPP を水素発生反応に用いた場合,他のTPP と比\n較して水素発生速度及び発生量が高い値を示した.","subitem_description_type":"Abstract"}]},"item_5_description_7":{"attribute_name":"引用","attribute_value_mlt":[{"subitem_description":"弘前大学教育学部紀要. 101, 2009, p.115-119","subitem_description_type":"Other"}]},"item_5_full_name_2":{"attribute_name":"著者(ヨミ)","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"6508","nameIdentifierScheme":"WEKO"}],"names":[{"name":"モリサキ, マナミ"}]},{"nameIdentifiers":[{"nameIdentifier":"6509","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ホリ, テルオ"}]}]},"item_5_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"6510","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Morisaki, Manami"}]},{"nameIdentifiers":[{"nameIdentifier":"6511","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Hori, 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Economics, Faculty of Education, Hirosaki University"},{"subitem_text_value":"Fiber Amenity Engineering Course, Graduate School of Engineering, University of Fukui"}]},"item_5_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"森崎, 真奈美"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"堀, 照夫"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-03-12"}],"displaytype":"detail","filename":"BFEduHirosaki_101_115.pdf","filesize":[{"value":"2.0 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