{"created":"2023-05-15T09:04:21.991446+00:00","id":5438,"links":{},"metadata":{"_buckets":{"deposit":"37ecf12e-2706-430e-893d-4060efb76655"},"_deposit":{"created_by":11,"id":"5438","owners":[11],"pid":{"revision_id":0,"type":"depid","value":"5438"},"status":"published"},"_oai":{"id":"oai:hirosaki.repo.nii.ac.jp:00005438","sets":["686:942:944"]},"author_link":["19655","19657","19656"],"item_3_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2017","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"55","bibliographicPageEnd":"34698","bibliographicPageStart":"34694","bibliographicVolumeNumber":"7","bibliographic_titles":[{"bibliographic_title":"RSC ADVANCES"}]}]},"item_3_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A photoelectrochemical water-splitting system featuring an organo-photocathode of a p-n bilayer was studied, where WO3 was simultaneously utilized as a photoanode. Stoichiometric formation of H-2 and O-2 was found to occur due to the decomposition of water. In the reference system of a WO3 photoanode and Pt counter electrode, bias voltages more than 0.4 V were needed to be applied for water splitting; however, the present system successfully led to water decomposition by applying only a low voltage of 0.1 V to the system. In the present water-splitting system, oxidizing and reducing powers can be separately generated at the WO3 photoanode and organo-photocathode, respectively, which is distinct from the reference system. Furthermore, electron transfer from WO3 (conduction band) to the hole-retained p-type layer (valence band) in the organo-photocathode can efficiently occur for completing the photoelectrochemical process, thus, resulting in a high concentration of holes available for rate-limiting O-2 evolution at WO3 on the basis of efficient charge separation.","subitem_description_type":"Abstract"}]},"item_3_radio_42":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_radio_item":"Article"}]},"item_3_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1039/c7ra05272c","subitem_relation_type_select":"DOI"}}]},"item_3_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2046-2069","subitem_source_identifier_type":"ISSN"}]},"item_3_text_4":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"Department of Frontier Materials Chemistry, Graduate School of Science and Technology, Hirosaki University"},{"subitem_text_value":"Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology"},{"subitem_text_value":"Department of Frontier Materials Chemistry, Graduate School of Science and Technology, Hirosaki University"}]},"item_3_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"kawai, Yuto"}],"nameIdentifiers":[{"nameIdentifier":"19655","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nagai, Keiji"}],"nameIdentifiers":[{"nameIdentifier":"19656","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Abe, Toshiyuki"}],"nameIdentifiers":[{"nameIdentifier":"19657","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-03-04"}],"displaytype":"detail","filename":"c7ra05272c_1.pdf","filesize":[{"value":"367.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"c7ra05272c_1","url":"https://hirosaki.repo.nii.ac.jp/record/5438/files/c7ra05272c_1.pdf"},"version_id":"0fb5a5d7-2120-4dc5-8b42-a14c63945ed8"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"A visible-light-induced photoelectrochemical water-splitting system featuring an organophotocathode along with a tungsten oxide photoanode","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"A visible-light-induced photoelectrochemical water-splitting system featuring an organophotocathode along with a tungsten oxide photoanode"}]},"item_type_id":"3","owner":"11","path":["944"],"pubdate":{"attribute_name":"公開日","attribute_value":"2019-03-04"},"publish_date":"2019-03-04","publish_status":"0","recid":"5438","relation_version_is_last":true,"title":["A visible-light-induced photoelectrochemical water-splitting system featuring an organophotocathode along with a tungsten oxide photoanode"],"weko_creator_id":"11","weko_shared_id":-1},"updated":"2023-05-16T06:20:53.507168+00:00"}