| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2019-03-04 |
| タイトル |
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タイトル |
A visible-light-induced photoelectrochemical water-splitting system featuring an organophotocathode along with a tungsten oxide photoanode |
| 言語 |
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言語 |
eng |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 著者 |
kawai, Yuto
Nagai, Keiji
Abe, Toshiyuki
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| 著者所属 |
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Department of Frontier Materials Chemistry, Graduate School of Science and Technology, Hirosaki University |
| 著者所属 |
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Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology |
| 著者所属 |
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Department of Frontier Materials Chemistry, Graduate School of Science and Technology, Hirosaki University |
| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
A photoelectrochemical water-splitting system featuring an organo-photocathode of a p-n bilayer was studied, where WO3 was simultaneously utilized as a photoanode. Stoichiometric formation of H-2 and O-2 was found to occur due to the decomposition of water. In the reference system of a WO3 photoanode and Pt counter electrode, bias voltages more than 0.4 V were needed to be applied for water splitting; however, the present system successfully led to water decomposition by applying only a low voltage of 0.1 V to the system. In the present water-splitting system, oxidizing and reducing powers can be separately generated at the WO3 photoanode and organo-photocathode, respectively, which is distinct from the reference system. Furthermore, electron transfer from WO3 (conduction band) to the hole-retained p-type layer (valence band) in the organo-photocathode can efficiently occur for completing the photoelectrochemical process, thus, resulting in a high concentration of holes available for rate-limiting O-2 evolution at WO3 on the basis of efficient charge separation. |
| 書誌情報 |
RSC ADVANCES
巻 7,
号 55,
p. 34694-34698,
発行日 2017
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| ISSN |
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収録物識別子タイプ |
ISSN |
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収録物識別子 |
2046-2069 |
| DOI |
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関連タイプ |
isIdenticalTo |
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識別子タイプ |
DOI |
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関連識別子 |
10.1039/c7ra05272c |
| 著者版フラグ |
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出版タイプ |
VoR |
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出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| 資源タイプ |
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値 |
Article |
c7ra05272c_1 (367.0 kB)
